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Thermoregulated phase-separable phosphine ruthenium complex for hydrogenation catalysis

โœ Scribed by Yanhua Wang; Xiaowei Wu; Fang Cheng; Zilin Jin

Book ID
104422203
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
90 KB
Volume
195
Category
Article
ISSN
1381-1169

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Hydroformylation of diisobutylene using
Hydroformylation of diisobutylene using thermoregulated phase-separable phosphine rhodium complex catalyst
โœ Yanhua Wang; Jingyang Jiang; Fang Cheng; Zilin Jin ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 75 KB

Based on the critical solution temperature (CST) of non-ionic phosphine ligand, a thermoregulated phase-separable catalyst formed in situ from P[p-C 6 H 4 O(CH 2 CH 2 O) n H] 3 (PETPP, n = 10) and RhCl 3 โ€ข3H 2 O was applied for the first time in the hydroformylation of diisobutylene. It was found th