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Thermoregulated Phase-Separable Phosphine Rhodium Complex Catalyst for Hydroformylation of Cyclohexene

✍ Scribed by Yanhua Wang; Jingyang Jiang; Xiaowei Wu; Fang Cheng; Zilin Jin

Book ID
110335550
Publisher
Springer US
Year
2002
Tongue
English
Weight
263 KB
Volume
79
Category
Article
ISSN
1011-372X

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Hydroformylation of diisobutylene using
Hydroformylation of diisobutylene using thermoregulated phase-separable phosphine rhodium complex catalyst
✍ Yanhua Wang; Jingyang Jiang; Fang Cheng; Zilin Jin πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 English βš– 75 KB

Based on the critical solution temperature (CST) of non-ionic phosphine ligand, a thermoregulated phase-separable catalyst formed in situ from P[p-C 6 H 4 O(CH 2 CH 2 O) n H] 3 (PETPP, n = 10) and RhCl 3 β€’3H 2 O was applied for the first time in the hydroformylation of diisobutylene. It was found th