THERMOPHYSICAL PROPERTIES OF THE LANTHANIDE OXIDES. I. HEAT CAPACITIES, THERMODYNAMIC PROPERTIES, AND SOME ENERGY LEVELS OF LANTHANUM(III) AND NEODYMIUM(III) OXIDES FROM 5 TO 350°K. 1
✍ Scribed by Justice, Bruce H.; Westrum, Edgar F.
- Book ID
- 121838814
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 1008 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0022-3654
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Heat-capacity measurements made on zone-refined rods of LaB 6 , NdB 6 , and GdB 6 revealed no anomalies in diamagnetic LaB 6 , but paramagnetic NdB 6 showed a cooperative λ-type transition associated with antiferromagnetic ordering near T /K = (8.4 ± 0.2) with trs S o /R = (1.39 ± 0.06) and a GdB 6
The heat capacity of ammonium hexabromotellurate (NH4)2TeBr6 was measured at temperatures from T = 5 K to T = 345 K by adiabatic calorimetry. Two l-shaped transitions were present, one at T = (193.25 2 0.05) K, with DtrsS°m = (1.145 2 0.010)•R, and another at T = (212.2 2 0.2) K, with DtrsS°m = (0.1