The heat capacity of ammonium hexachloroosmate (NH4)2OsCl6 was measured at temperatures from T = 6 K to 325 K by adiabatic calorimetry. Two small anomalous regions were observed in the heat-capacity against temperature plot. The lower one, from 80 E (T/K) E 140, had an excess molar enthalpy of (21.1
Thermodynamics of ammonium halogenated tellurides: III. Heat capacity, phase transitions, and thermodynamic properties of (NH4)2TeBr6at temperatures from 5 K to 350 K
β Scribed by Jane E. Callanan; Ron D. Weir; Edgar F. Westrum; Jr.
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 457 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0021-9614
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β¦ Synopsis
The heat capacity of ammonium hexabromotellurate (NH4)2TeBr6 was measured at temperatures from T = 5 K to T = 345 K by adiabatic calorimetry. Two l-shaped transitions were present, one at T = (193.25 2 0.05) K, with DtrsSΒ°m = (1.145 2 0.010)β’R, and another at T = (212.2 2 0.2) K, with DtrsSΒ°m = (0.122 2 0.010)β’R. Smoothed values of the standard thermodynamic quantities for pure (NH4)2TeBr6 are tabulated up to T = 350 K.
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