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Thermolysis of Polyhedral Oligomeric Silsesquioxane (POSS) Macromers and POSS−Siloxane Copolymers

✍ Scribed by Mantz, R. A.; Jones, P. F.; Chaffee, K. P.; Lichtenhan, J. D.; Gilman, J. W.; Ismail, I. M. K.; Burmeister, M. J.

Book ID
121272040
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
286 KB
Volume
8
Category
Article
ISSN
0897-4756

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This review describes the synthesis and properties of homopolymers and copolymers of monomers containing inorganic-organic hybrid polyhedral oligomeric silsesquioxane (POSS) structures. Monomers, such as styryl-POSS, methacrylate-POSS, norbornyl-POSS, vinyl-POSS, epoxy-POSS, and siloxane-POSS, are i

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A series of polyhedral oligomeric silsesquioxanes (POSS) monomers bearing silane or a-olefin substituents have been prepared and their chemistry explored. Both the POSS silanes and a-olefin monomers readily participate in hydrosilation chemistry and have been used as starting materials for the prepa

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A diverse and entirely new class of monomer and polymer technology based on polyhedral oligomeric silsesquioxane (POSS) reagents has been developed. POSS reagents are unique in that they are physically large (approx. 15 A ˚diameter and 1000 amu) and are composed of a robust silicon-oxygen framework