ChemInform Abstract: Functionalized Polyhedral Oligosilsesquioxane (POSS) Macromers: New Graftable POSS Hydride, POSS α-Olefin, POSS Epoxy, and POSS Chlorosilane Macromers and POSS-Siloxane Triblocks.

Functionalized polyhedral oligosilsesqui

Functionalized polyhedral oligosilsesquioxane (POSS) macromers: new graftable POSS hydride, POSS α-olefin, POSS epoxy, and POSS chlorosilane macromers and POSS–siloxane triblocks

✍ Edward G. Shockey; Alan G. Bolf; Paul F. Jones; Joseph J. Schwab; Kevin P. Chaff 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 183 KB

A series of polyhedral oligomeric silsesquioxanes (POSS) monomers bearing silane or a-olefin substituents have been prepared and their chemistry explored. Both the POSS silanes and a-olefin monomers readily participate in hydrosilation chemistry and have been used as starting materials for the prepa