Thermolysis of endo, exo-Tetracyclo[6.1.0.02,4.05,7]nonane (trans-Tris-σ-homobenzene)

✍ Scribed by Dr. Werner Spielmann; Dr. Dieter Kaufmann; Prof. Dr. Armin de Meijere

• Publisher: John Wiley and Sons
• Year: 1978
• Tongue: English
• Weight: 234 KB
• Volume: 17
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.197804401

✦ Synopsis

More detailed information about the mechanism of the major reactions comes from an examination of the [3,6-'*CZ]labeled hydrocarbon ( I b ) prepared by a new method. Addition of dichlorocarbene (from "CHC13) to 1,3-cyclohexadiene ~_ _ -_ _ -_ _ ~.