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cis, trans-Tetracyclo[6.1.0.02,4.05,7]nonane, “trans-Trishomobenzene”

✍ Scribed by Dipl.-Chem. Martin Engelhard; Prof. Dr. Wolfgang Lüttke


Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
131 KB
Volume
11
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Thermolysis of endo, exo-Tetracyclo[6.1.
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More detailed information about the mechanism of the major reactions comes from an examination of the [3,6-'\*CZ]labeled hydrocarbon ( I b ) prepared by a new method. Addition of dichlorocarbene (from "CHC13) to 1,3-cyclohexadiene ~\_ \_ -\_ \_ -\_ \_ ~.

Hexacyclo[4.4.0.02,4.03,9.05,7.08,10]dec
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The two hydrogen atoms of ( I ) that are bonded to phosphorus react no further with BH; because of their low acidity. Stepwise removal of both these protons is, however, possible by reaction of ( I ) with n-butyllithium ; trisboranephosphite (2) and tetgakisboranephosphate (3), which are isoelectron

ChemInform Abstract: Stereocontrolled Pr
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Stereocontrolled Preparation of cis-and trans-2,6-Dialkylpiperidines via Diastereoselective Reaction of 1-Aza-4-oxabicyclo[4.3.0]nonane Derivatives with Grignard Reagents. -A simple procedure for the enantioselective preparation of the title compounds from known 1-aza-4oxabicyclo[4.3.0]nonane deriv