Thermolysis and photolysis of 3-chloro-3-benzyldiazirines in alkenes; evidence for a carbene-alkene complex
β Scribed by Liu, Michael T. H.; Soundararajan, N.; Paike, N.; Subramanian, R.
- Book ID
- 126827306
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 552 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0022-3263
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The thermal reaction of 2-haloethoxy-and 3-chloropropoxy(alkenyl)carbene complexes of chromium with electronically neutral alkenes furnished diastereoselectively the corresponding 1-haloalkoxy-1-vinylcyclopropanes that, subjected to subsequent halogen Β± lithium exchange reactions, provided vinylcycl
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