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ChemInform Abstract: 2- and 3-Haloalkoxy Fischer Carbene Complexes of Chromium as Synthons for Either Hydroxycyclopropanation or Oxaspirocyclopropanation of Alkenes.

✍ Scribed by Jose Barluenga; Salome Lopez; Andres A. Trabanco; Josefa Florez


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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Abstract

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2- and 3-Haloalkoxy Fischer Carbene Comp
✍ José Barluenga; Salomé López; Andrés A. Trabanco; Josefa Flórez 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 139 KB

The thermal reaction of 2-haloethoxy-and 3-chloropropoxy(alkenyl)carbene complexes of chromium with electronically neutral alkenes furnished diastereoselectively the corresponding 1-haloalkoxy-1-vinylcyclopropanes that, subjected to subsequent halogen ± lithium exchange reactions, provided vinylcycl