𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Thermokinetics on the reaction of formation of the ternary complex Nd[(C5H8NS2)3(C12H8N2)]

✍ Scribed by Xue-Zhong Fan; Xiang-Xin Meng; San-Ping Chen; Bao-Juan Jiao; Yi-Xia Ren; Sheng-Li Gao; Qi-Zhen Shi

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
434 KB
Volume
22
Category
Article
ISSN
0256-7660

No coin nor oath required. For personal study only.

✦ Synopsis

The title ternary complex Nd [(C5H8NS&(ClzH8N2)] has been synthesized in absolute ethanol by the reaction of NdCI3-3.74H20 with ammonium pyrrolidmyldifhiocaboxylate (APDC) and 1.10-phenanthroline (phen*H20) at air atmosphere without any cautions against moisture. The bonding characteristics of the complex were characterized by JR, showing that Nd3+ is bonded with sulfur atom in the APDC and coordinated with nitrogen atom in the phen. TG-DTG investigation indicates that the title complex was decomposed into NdzS3 and deposited carbon in one step where Nd2S3 predominated in the final products. The enthalpy change of formation of the reaction on the title complex in liquid-phase has been determined by a microcalorimeter. Thermodynamic parameters (the activation enthalpy, the activation entropy and the activation free energy) and kinetics parameters (the rate constant, the apparent activation energy, the pre-exponential constant and the reaction order) of the title reaction have been calculated. The enthalpy change of the sotid-phase reaction has been obtained by a thennochemistry cycle.

πŸ“œ SIMILAR VOLUMES

Kinetic study of the gas-phase reaction
Kinetic study of the gas-phase reaction c-C5H10 + I2 ⇄ c-C5H8 + 2HI the heat of formation of cyclopentyl radical
✍ Shozo Furuyama; David M. Golden; Sidney W. Benson πŸ“‚ Article πŸ“… 1970 πŸ› John Wiley and Sons 🌐 English βš– 389 KB

The kinetics of the gas-phase dehydrogenation of cyclopentane to cyclopentene is found to be consistent with a slow attack by a n I atom (step 4, text) on cyclopentane in the range 282-382OC. The measured rate constants fit the Xrrhenius equation, log k, = 11.95 f 0.08 -(24.9 f 0.23)/0 1 mole-l sec-

Formal Three-Electron Reduction by an f-
Formal Three-Electron Reduction by an f-Element Complex: Formation of [{(C5Me5)(C8H8)U}2(C8H8)] from Cyclooctatetraene and [(C5Me5)3U]
✍ William J. Evans; Gregory W. Nyce; Joseph W. Ziller πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 100 KB πŸ‘ 1 views

Reduction reactions involving more than two electrons are not common for metal complexes containing just one metal. In f-element chemistry, multielectron reductions from monometallic species are particularly rare since the common lowvalent ions Th III , U III , Eu II , Yb II , Sm II , and Tm II ty

Kinetic study of the gas-phase reaction
Kinetic study of the gas-phase reaction c-C5H8 + I2 ⇄ c-C5H6 + 2HI the heat of formation and the stabilization energy of the cyclopentenyl radical
✍ Shozo Furuyama; David M. Golden; Sidney W. Benson πŸ“‚ Article πŸ“… 1970 πŸ› John Wiley and Sons 🌐 English βš– 276 KB πŸ‘ 1 views

The gas-phase dehydrogenation of cyclopentene to cyclopentadiene catalyzed by iodine in. the range 178-283'C has been found to obey a rate law consistent with the slow rate-determining step, I + c-C5Hs --t HI + c-C5H, , log [ka/(l moleL1 sec-')I = 10.25 \* 0.08 -(12.26 f 0.18)/0, where 0 = 2.303RT i

New Mixed Ligand Organotellurium(IV) Com
New Mixed Ligand Organotellurium(IV) Compounds Containing Dithiocarbamates and the More Flexible Imidotetraphenyldithiodiphosphinates. The Crystal Structures of C8H8Te(S2CNEt2)[(SPPh2)2N] Β· H2O, C8H8Te(S2CNC5H10)[(SPPh2)2N], and C8H8Te(S2CNC4H8S)[(SPPh2)2N]
✍ Graciela Canseco-Melchor; VerΓ³nica GarcΓ­a-Montalvo; R. Alfredo Toscano; Raymundo πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 German βš– 168 KB πŸ‘ 3 views