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Thermodynamics of the amalgam cell {LixHg1−x| Li2SO4(m) | Hg2SO4| Hg} in water, (methanol + water), and (acetonitrile + water) solvent mixtures

✍ Scribed by C.L. Faverio; P.R. Mussini; T. Mussini


Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
191 KB
Volume
30
Category
Article
ISSN
0021-9614

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✦ Synopsis


¨q ¨y

where M and X indicate electrodes reversible to the cation M zq and to the anion X zy , respectively, M zq X zy is the corresponding general strong binary electrolyte ¨q ¨y at molality m, and Z is a binary aqueous-organic solvent mixture, is of key importance not only to electrochemists but also to electroanalysts and corrosion scientists. Ž1. In particular, knowledge of fundamental thermodynamic quantities a Ž .


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The electromotive force E of the cell {NaxHg1-x =NaCl(m)=AgCl=Ag} has been measured at the temperature 298.15 K as a function of the mole fraction x of Na metal in amalgams and of the molality m of NaCl in (methanol + water) solvent mixtures containing up to 0.8 mass fraction of methanol, with relat

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The electromotive force E of the cell: {Mex Hg1-x =MeCl(m)=AgCl=Ag} (where Me = Na, K or Cs), has been measured at the temperature 298.15 K as a function of the mole fraction x of the metal Me in amalgams and of the molality m of the alkali chloride MeCl in (ethanol + water) solvent mixtures contain