The electromotive force E of the cell {NaxHg1-x =NaCl(m)=AgCl=Ag} has been measured at the temperature 298.15 K as a function of the mole fraction x of Na metal in amalgams and of the molality m of NaCl in (methanol + water) solvent mixtures containing up to 0.8 mass fraction of methanol, with relat
Thermodynamics of the amalgam cell {LixHg1−x| Li2SO4(m) | Hg2SO4| Hg} in water, (methanol + water), and (acetonitrile + water) solvent mixtures
✍ Scribed by C.L. Faverio; P.R. Mussini; T. Mussini
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 191 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0021-9614
No coin nor oath required. For personal study only.
✦ Synopsis
¨q ¨y
where M and X indicate electrodes reversible to the cation M zq and to the anion X zy , respectively, M zq X zy is the corresponding general strong binary electrolyte ¨q ¨y at molality m, and Z is a binary aqueous-organic solvent mixture, is of key importance not only to electrochemists but also to electroanalysts and corrosion scientists. Ž1. In particular, knowledge of fundamental thermodynamic quantities a Ž .
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The electromotive forces E of the amalgam cells {Li x Hg 1-x | LiCl (m) | AgCl | Ag} and {Li x Hg 1-x | LiBr (m) | AgBr | Ag} have been measured as a function of the mole fraction x of Li metal in amalgams and of the molalities m of LiCl as well as LiBr at T = 298.15 K. For LiCl, the solvents invest
The electromotive force E of the amalgam cell {K x Hg 1-x |KCl(m)|AgCl|Ag} has been measured as a function of the mole fraction x of K metal in amalgams and of the molality m of KCl in (ethylene glycol + water), (acetonitrile + water), and (1,4dioxane + water) solvent mixtures containing up to 0.8 m
The electromotive force E of the cell: {Mex Hg1-x =MeCl(m)=AgCl=Ag} (where Me = Na, K or Cs), has been measured at the temperature 298.15 K as a function of the mole fraction x of the metal Me in amalgams and of the molality m of the alkali chloride MeCl in (ethanol + water) solvent mixtures contain