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Thermodynamics of the amalgam cell {KxHg1 − x| KCl (m)| AgCl | Ag }and primary medium effects upon KCl in { ethylene glycol  +  water }, { acetonitrile  +  water }, and { 1,4-dioxane  +  water } solvent mixtures

✍ Scribed by A. Manzoni; P.R. Mussini; T. Mussini


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
242 KB
Volume
32
Category
Article
ISSN
0021-9614

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✦ Synopsis


The electromotive force E of the amalgam cell {K x Hg 1-x |KCl(m)|AgCl|Ag} has been measured as a function of the mole fraction x of K metal in amalgams and of the molality m of KCl in (ethylene glycol + water), (acetonitrile + water), and (1,4dioxane + water) solvent mixtures containing up to 0.8 mass fraction of the organic component, at the temperature 298.15 K. The respective standard electromotive forces E o


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The electromotive forces E of the amalgam cells {Li x Hg 1-x | LiCl (m) | AgCl | Ag} and {Li x Hg 1-x | LiBr (m) | AgBr | Ag} have been measured as a function of the mole fraction x of Li metal in amalgams and of the molalities m of LiCl as well as LiBr at T = 298.15 K. For LiCl, the solvents invest

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The electromotive force (e.m.f.) E of the cell Pt|H 2 (p)|HCl(m) in Z|AgCl|Ag in {glycerol (G) + water (W)} solvents, Z = (G + W), up to glycerol mass fraction w G = 0.7 has been measured within the temperature range from 273.15 K to 313.15 K at HCl molalities up to 0.1 mol • kg -1 . On this basis,