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Thermodynamics of polyaddition reactions of silicon and germanium dihydrides with bis(ethynyl) derivatives of silicon and germanium

✍ Scribed by N. K. Lebedev; E. G. Kiparisova; B. V. Lebedev; A. M. Sladkov; N. A. Vasneva

Book ID
112442981
Publisher
Springer
Year
1980
Tongue
English
Weight
238 KB
Volume
29
Category
Article
ISSN
1573-9171

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The synthesis of novel bis(amidinate) silicon and germanium complexes is described. The reaction of two equiv. of [MeC(NiPr) 2 ]Li β€’ THF (1) with SiCl 4 , GeCl 4 or GeCl 2 β€’dioxane affords [MeC(NiPr) 2 ] 2 SiCl 2 (2), [MeC(NiPr) 2 ] 2 GeCl 2 (3) and