Thermodynamics of gas solubility: Relation between equation-of-state and activity-coefficient models
β Scribed by Eberhard Bender; Udo Klein; Wolfgang Ph. Schmitt; John M. Prausnitz
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 724 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0378-3812
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π SIMILAR VOLUMES
A new activity coefficient model was developed from excess Gibbs free energy in the form G ex ΒΌ cA a x 1 b . . . x n b . The constants of the proposed model were considered to be function of solute and solvent dielectric constants, Hildebrand solubility parameters and specific volumes of solute and
Emf measurements of the cells of the type Pt; HB (g, 1 atm)/HCl (m) in 5 wt-% 1-butanol, AgCl/Ag at five different temperatures ranging from 545Β°C were used to derive (i) the standard potentials of the silver/silver-chloride electrode, (ii) the mean activity coefficients of HCI, (iii) the primary an