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Thermodynamics of Formation, Reorganization, and Melting of Confined Nanometer-Sized Polymer Crystals

✍ Scribed by Röttele, Andreas; Thurn-Albrecht, Thomas; Sommer, Jens-Uwe; Reiter, Günter

Book ID
118017142
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
105 KB
Volume
36
Category
Article
ISSN
0024-9297

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The thermodynamic relations between the melting point (MP) and the size of crystals are derived by the use of the Kelvin equation. The results show that the MP depression increases with a decrease in size of a crystal and that there exists the lowest MP when the partial derivative of the surface ten