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Phenomenological and Thermodynamic Aspects of Melting and Formation of Polymer Crystals in the Presence of Liquids

✍ Scribed by L. N. Mizerovskii; K. V. Pochivalov


Book ID
110317563
Publisher
Springer US
Year
2001
Tongue
English
Weight
69 KB
Volume
33
Category
Article
ISSN
0015-0541

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✍ Yongqiang Xue; Qingsheng Zhao; Chunhui Luan πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 41 KB

The thermodynamic relations between the melting point (MP) and the size of crystals are derived by the use of the Kelvin equation. The results show that the MP depression increases with a decrease in size of a crystal and that there exists the lowest MP when the partial derivative of the surface ten