Thermodynamics of aqueous solutions of nonelectrolytes. II. Enthalpies of transfer of 1-methyl-2-pyrrolidinone from water to many aqueous alcohols
β Scribed by Fumio Kimura; Sachio Murakami; Ryoichi Fujishiro
- Publisher
- Springer US
- Year
- 1975
- Tongue
- English
- Weight
- 286 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0095-9782
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The enthalpies of transfer of proteins from aqueous solution to alcohol-water solutions are used as probes of solvent-accessible surface for these proteins. Enthalpies of transfer to 10 wt% ethanol solutions are determined calorimetrically for the native proteins ribonuclease A, lysozyme, and ovalbu
Electromotive force measurements of the cell: KSCN(m,) HCIO,(mz) Pt. H, AgSCWAg Dioxaae(X) % Water(y) % have been made at IS, 25,35 and 45Β°C for solvent compositions X = 10,20,30 and 40 % (w/w) of dioxane. lltesehavebcen used toevaluate thestandard potentialsofthecelland themtiotu thermodynw&functio