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Thermodynamic studies with silver—silver thiocyanate electrodes: transfer of (H+ SCN−) from aqueous to dioxane—water solutions

✍ Scribed by Bijoy K. Das; Prasanna K. Das

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 252 KB
Volume: 26
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(81)85048-7

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✦ Synopsis

Electromotive force measurements of the cell: KSCN(m,) HCIO,(mz) Pt. H, AgSCWAg Dioxaae(X) % Water(y) % have been made at IS, 25,35 and 45°C for solvent compositions X = 10,20,30 and 40 % (w/w) of dioxane. lltesehavebcen used toevaluate thestandard potentialsofthecelland themtiotu thermodynw&functions for the transfer of (H' SCN-) from water to the respective dioxaae-water medi The standard fr& energy of transfer values along with those for halogm acids are briefly discussed in relation to ion solvatian.

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