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Thermodynamics of Addition of CO, Isocyanide, and H2 to Rh(PR3)2Cl

✍ Scribed by Wang, Kun; Rosini, Glen P.; Nolan, Steven P.; Goldman, Alan S.


Book ID
127081384
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
899 KB
Volume
117
Category
Article
ISSN
0002-7863

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The addition reactions of CC13 radicals with cis-CzClzHz, trans-CzClzHz, and CzC13H in liquid cyclohexane-CC14 mixtures were studied between 323 and 448 K. The Arrhenius parameters of these reactions were competitively determined versus H-atom transfer from cyclohexane and addition to C2C14. The pre