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Thermodynamics, Kinetics, and Mechanism of the Stepwise Dissociation and Formation of Tris( l -lysinehydroxamato)iron(III) in Aqueous Acid

✍ Scribed by Wirgau, Joseph I.; Spasojević, Ivan; Boukhalfa, Hakim; Batinić-Haberle, Ines; Crumbliss, Alvin L.

Book ID
124053953
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
115 KB
Volume
41
Category
Article
ISSN
0020-1669

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✍ K. Sriramam; J. Sreelakshmi; L. Ramadevi; Ch. Ramakrishna 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 733 KB

The kinetics of dissociation of tris-2,2'-bipyridyl-iron(II) complex ion have been examined in aqueous acetic acid solutions. The reaction is first order in the complex ion; the dependence of rate on H' is somewhat like that observed in aqueous solutions approaching a limiting value at higher H' con