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Thermodynamic stability of chemical reactors

โœ Scribed by P. Costa; C. Trevissoi


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
707 KB
Volume
28
Category
Article
ISSN
0009-2509

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โœฆ Synopsis


Reference is made to the general criteria for thermodynamic stability of stationary states far from equilibrium recently established by Glansdortf and Prigogine, in order to find the global sufficient conditions for the continuous well-stirred tank reactor and for the catalytic particle. When the thermodynamic conditions are obtained in a form which permits their being symmetrically compared with the well-known necessary and sufficient kinetic conditions, it appears that the former are in fact more restrictive, but they may be led back to the kinetic conditions by isolating some particular features of the theory of normal modes.


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