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Thermodynamic significance of .rho.+ and .rho.- from substituent effects on the redox potentials of arylmethyl radicals

✍ Scribed by Sim, B. A.; Milne, P. H.; Griller, D.; Wayner, D. D. M.


Book ID
126179529
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
555 KB
Volume
112
Category
Article
ISSN
0002-7863

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Substituent effect on the redox potentia
✍ Wu Guo-Zhang; Leung (Xiaoguang Liang) Hiu-Kwong; Gan Wei-Xing πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 639 KB

meso-Substituent effect on the redox properties of octaethylporphyrin and its zinc(lI) and copper(I1) complexes are investigated with cyclic volatmmetry. The El/2 values were observed to correlate linearly with Hammett's d, constant for the first and second oxidation reaction and the first reduction