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Thermodynamic properties of crystalline phosphate Ba0.5Zr2(PO4)3over the temperature range fromT

✍ Scribed by V. I. Pet’kov; I. A. Shchelokov; A. V. Markin; N. N. Smirnova; M. V. Sukhanov

Book ID: 106447395
Publisher: Springer Netherlands
Year: 2010
Tongue: English
Weight: 320 KB
Volume: 102
Category: Article
ISSN: 0022-5215
DOI: 10.1007/s10973-010-0909-3

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The phosphate Cu I 0.5 Mn II 0.25 Zr 2 (PO 4 ) 3 can be obtained at 10003C by exchange reaction in Cu II 0.5 Zr 2 (PO 4 ) 3 . It crystallizes in the rhombohedral system (space group R3 ) with the parameters a h ‫؍‬ 8.8352(1) A s and c h ‫؍‬ 22.254(5) A s in the equivalent hexagonal cell. The structu