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Thermodynamic properties of a hindered rotator

✍ Scribed by J. Mahanty; D.D. Richardson


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
165 KB
Volume
34
Category
Article
ISSN
0009-2614

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✦ Synopsis


It is demcnstrated that a finite dimensional representation of the hamiltonian of a hindered rotator can be used toget reasonably accurate values of thermodyn;lmic properties, e.g., the specific heat of an assembly of such rotators. It is known that there is a large differencz between the classical values and quantum statistical values @'hen the height of the hinder& potential is small.


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