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Hindered rotation of CN− in KCN

✍ Scribed by David Smith

Publisher: Elsevier Science
Year: 1968
Tongue: English
Weight: 427 KB
Volume: 29
Category: Article
ISSN: 0022-3697
DOI: 10.1016/0022-3697(68)90129-7

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📜 SIMILAR VOLUMES

✍ D. Smith 📂 Article 📅 1967 🏛 Elsevier Science 🌐 English ⚖ 424 KB

Dynamic NMR study of hindered rotation a

Dynamic NMR study of hindered rotation around the CN bond in thiopiperidides

✍ Mariana Ciureanu; Victor E. Sahini; Felicia Cornea; Cornelia Cercasov; Mihai Con 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 356 KB 👁 1 views

## Abstract The barriers to internal rotation about the CN bond in several thiopiperidides have been determined by the NMR technique. It was found that the barrier height (Δ__G__^‡^) increases in the series cinnamoylthiopiperididem‐and __p__‐substituted cinnamoylthiopiperidides the barriers were s

Spin-rotation relaxation in rotor solid

Spin-rotation relaxation in rotor solid KCN

✍ Eun Kee Jeong; J.H Walton; Montee A Doverspike; Mark S Conradi 📂 Article 📅 1990 🏛 Elsevier Science ⚖ 293 KB

Hindered rotation in thioamides—II

✍ Kermit C. Ramey; David J. Louick; Philip W. Whitehurst; William B. Wise; Rabindr 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 800 KB

Hindered Internal Rotation in Cyanine Dy

Hindered Internal Rotation in Cyanine Dyes

✍ Prof. Dr. G. Scheibe; Doz. Dr. C. Jutz; Dr. W. Seiffert; Dipl.-Chem. D. Grosse 📂 Article 📅 1964 🏛 John Wiley and Sons 🌐 English ⚖ 113 KB

Rotation of CN in solid rare gases

✍ G. Schallmoser; A. Thoma; B.E. Wurfel; V.E. Bondybey 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 591 KB

The band shapes of the infrared fluorescence from the u= l-4 X '2 levels of CN isolated in rare gas matrices are investigated using a high-resolution Fourier-transform spectrometer. The spectra suggest nearly free rotation in solid Xe, with barriers to rotation increasing for the lighter rare gases.