Thermodynamic interpretation of solute–polymer interactions at infinite dilution

✍ Scribed by Khalid A. Karim; David C. Bonner

• Publisher: John Wiley and Sons
• Year: 1978
• Tongue: English
• Weight: 624 KB
• Volume: 22
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/app.1978.070220510

✦ Synopsis

Heats of solution a t infinite dilution of solutes in poly(ethy1 methacrylate) were estimated using gas-liquid chromatography over a temperature range of 417.74 K-427.55 K. The heat of solution is related to solute polarizability and dipole moment. Contributions of specific interactions such as hydrogen bonding and charge-transfer complexing to the enthalpy of solution were also determined.