Thermodynamic Data of Polymer Solutions at Elevated Pressures
β Scribed by Bernhard Wolf
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 42 KB
- Volume
- 207
- Category
- Article
- ISSN
- 1022-1352
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The gas chromatographic (GC) method for thermodynamic measurements of polymerβsolvent systems at finite concentration has been improved to extend its operating range from atmospheric pressure to over 70 atm and over 240Β°C. This paper describes the design and opertion of the equipment an
## Abstract The kinetic of ethene polymerization catalyzed by (^n^BuCp)~2~ZrCl~2~/Al^i^Bu~3~/[Me~2~PhNH]^+^[B(C~6~F~5~)~4~]^β^ has been investigated at 100 and 140βΒ°C at pressures from 2 to 7 MPa. The initial polymerization rate __R__~p0~ increases linearly with increasing catalyst concentration, w
A method for testing the thermodynamic consistency of binaiy and isothemal vapor-liquid equilibrium data at moderate and high pressures is proposed, using a 9-4p approach. The Redlich-Kwong-Soave equation of state with Huron-Kdal mixing rules at infinite pressure is used in the data-reduction proced