𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Thermodynamic data interpretation of the ion association process in mixed solvents

✍ Scribed by Yu. Fialkov; V. Chumak


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
401 KB
Volume
84
Category
Article
ISSN
0167-7322

No coin nor oath required. For personal study only.

✦ Synopsis


Some approaches have been developed which allow to divide thermodynamic functions of the ion association processes in two components. The first component belongs to the process, the second one is caused by the temperature dependence of the dielectric permittivity of the solvent. The theory is confirmed by numerous examples which deal with the ion association process of different electrolytes in binary mixed solvents.


πŸ“œ SIMILAR VOLUMES


Conductivities and ion association of 1:
✍ M. Salomon; E. Plichta πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 English βš– 508 KB

Molar conductivities of the 1: 1 electrolytes LiCIO+ LiAsF,, n-Bu.,NCIO.+ and n-Bu,NBPh, were measured in mixtures of propylene carbonate and dimethoxymethane over the concentration range 0.01-l x 10m4 mol dm-'. In all cases a maximum in molar conductivity (and hence in electroiytic conductivity) i

Calculation of the thermodynamic charact
✍ Yu.Ya. Fialkov; V.Yu. Gorbachev; T.A. Kamenskaya πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 350 KB

Technique for calculation of the 'van't Hoff's' or temperature components of the thermodynamic characteristics of ionic association processes taking place in individual solvents is proposed. The calculation is based on the equations of ionic association constant most common in literature. Advantages