𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Calculation of the thermodynamic characteristics of ionic association processes in individual solvents

✍ Scribed by Yu.Ya. Fialkov; V.Yu. Gorbachev; T.A. Kamenskaya

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
350 KB
Volume
89
Category
Article
ISSN
0167-7322

No coin nor oath required. For personal study only.

✦ Synopsis

Technique for calculation of the 'van't Hoff's' or temperature components of the thermodynamic characteristics of ionic association processes taking place in individual solvents is proposed. The calculation is based on the equations of ionic association constant most common in literature. Advantages of using the 'van't Hoff's' components rather than the integral thermodynamic characteristics for analysis of ionic equilibria are considered.

πŸ“œ SIMILAR VOLUMES

Thermodynamic data interpretation of the
Thermodynamic data interpretation of the ion association process in mixed solvents
✍ Yu. Fialkov; V. Chumak πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 401 KB

Some approaches have been developed which allow to divide thermodynamic functions of the ion association processes in two components. The first component belongs to the process, the second one is caused by the temperature dependence of the dielectric permittivity of the solvent. The theory is confir

Ionic Association of the Ionic Liquids [
Ionic Association of the Ionic Liquids [C4mim][BF4], [C4mim][PF6], and [Cnmim]Br in Molecular Solvents
✍ Huiyong Wang; Jianji Wang; Sheli Zhang; Yuanchao Pei; Kelei Zhuo πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 240 KB

## Abstract __Considering the ionic nature of ionic liquids (ILs), ionic association is expected to be essential in solutions of ILs and to have an important influence on their applications. Although numerous studies have been reported for the ionic association behavior of ILs in solution, quantita