Thermodynamic characteristics of self-associated solvents
β Scribed by Zaichikov, A. M.; Makarov, S. V.
- Book ID
- 118725518
- Publisher
- Springer
- Year
- 2012
- Tongue
- English
- Weight
- 237 KB
- Volume
- 82
- Category
- Article
- ISSN
- 1070-3632
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π SIMILAR VOLUMES
Technique for calculation of the 'van't Hoff's' or temperature components of the thermodynamic characteristics of ionic association processes taking place in individual solvents is proposed. The calculation is based on the equations of ionic association constant most common in literature. Advantages
For alcohol-ahphak hydrocarbon solutions, the athermal assoclakd solut~oon theory of Wlehe and Bagley 1s modlfied by mtroducmg a physical interaction term of the Scatchard-Hfidebrand type expression Good fits between the modlfied theory and experunental data for the excess Gibbs free energy of mlxmg