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Thermodynamic and structural considerations of insertion reactions in lithium vanadium bronze structures

✍ Scribed by Bor Yann Liaw; Ian D. Raistrick; Robert A. Huggins


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
489 KB
Volume
45
Category
Article
ISSN
0167-2738

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We have studied the structural modifications that occur during electrochemical insertion of lithium into the spinel compound In 16 Fe 8 S 32 . Studies by X-ray diffraction (Rietveld analysis) and Mo¨ssbauer spectroscopy of the lithiated products indicate that some cation migration takes place during