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Kinetics and thermodynamics of the lithium insertion reaction in spinel phase LixMn2O4

โœ Scribed by J. Barker; K. West; Y. Saidi; R. Pynenburg; B. Zachau-Christiansen; R. Koksbang


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
318 KB
Volume
54
Category
Article
ISSN
0378-7753

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Electrochemical and x-ray diffraction measurements have been performed on two lithium deficient lithium manganese oxide phases, namely Li,,,~Mn,O, and Lip,csMntO,. These materials were prepared by a chemical oxidative treatment of the parent LiMn,O, spmel phase in acidic conditions. The results are

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## Thermodynamic, kinetic and impedance studies of the Li//Li,Mn,O, (spine1 phase) have been carried out using a polymerbased electrolyte system. There appear to be three voltage ranges for the reversible lithium intercalation reaction, centered around 4, 2.9 and 1.1 V versus L&i+. A ceil utilizin