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Thermodynamic and Kinetic Control over the Reduction Mechanism of the Pd 3 (dppm) 3 (CO)(I) + Cluster

✍ Scribed by Lemaître, Frédéric; Brevet, David; Lucas, Dominique; Vallat, Alain; Mugnier, Yves; Harvey, Pierre D.


Book ID
127176493
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
94 KB
Volume
41
Category
Article
ISSN
0020-1669

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Generation, Characterization, and Electr
✍ Cyril Cugnet; Dominique Lucas; Edmond Collange; Bernard Hanquet; Alain Vallat; Y 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 502 KB

## Abstract Addition of formate on the dicationic cluster [Pd~3~(dppm)~3~(μ~3~‐CO)]^2+^ (dppm=bis(diphenylphosphinomethane) affords quantitatively the hydride cluster [Pd~3~(dppm)~3~(μ~3~‐CO)(μ~3~‐H)]^+^. This new palladium–hydride cluster has been characterised by ^1^H NMR, ^31^P NMR and UV/Vis sp