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Electrochemically Induced C−Br and C−I Bond Activation by the Pd 3 (dppm) 3 CO 2+ Cluster, and Characterization of the Reactive Pd 3 (dppm) 3 CO + Intermediate: The First Confidently Identified Paramagnetic Pd Cluster

✍ Scribed by Brevet, David; Lucas, Dominique; Cattey, Hélène; Lemaître, Frédéric; Mugnier, Yves; Harvey, Pierre D.


Book ID
127330033
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
38 KB
Volume
123
Category
Article
ISSN
0002-7863

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Generation, Characterization, and Electr
✍ Cyril Cugnet; Dominique Lucas; Edmond Collange; Bernard Hanquet; Alain Vallat; Y 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 502 KB

## Abstract Addition of formate on the dicationic cluster [Pd~3~(dppm)~3~(μ~3~‐CO)]^2+^ (dppm=bis(diphenylphosphinomethane) affords quantitatively the hydride cluster [Pd~3~(dppm)~3~(μ~3~‐CO)(μ~3~‐H)]^+^. This new palladium–hydride cluster has been characterised by ^1^H NMR, ^31^P NMR and UV/Vis sp