Generation, Characterization, and Electr
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Cyril Cugnet; Dominique Lucas; Edmond Collange; Bernard Hanquet; Alain Vallat; Y
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Article
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2007
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John Wiley and Sons
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English
⚖ 502 KB
## Abstract Addition of formate on the dicationic cluster [Pd~3~(dppm)~3~(μ~3~‐CO)]^2+^ (dppm=bis(diphenylphosphinomethane) affords quantitatively the hydride cluster [Pd~3~(dppm)~3~(μ~3~‐CO)(μ~3~‐H)]^+^. This new palladium–hydride cluster has been characterised by ^1^H NMR, ^31^P NMR and UV/Vis sp