Thermodynamic analysis of the morphology of monomer-adsorbed, cross-linked polymer particles prepared by the dynamic swelling method and seeded polymerization
β Scribed by Hideto Minami; Zhaoqun Wang; Tsuyoshi Yamashita; Masayoshi Okubo
- Publisher
- Springer
- Year
- 2003
- Weight
- 508 KB
- Volume
- 281
- Category
- Article
- ISSN
- 0340-255X
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π SIMILAR VOLUMES
For the purpose of extending the size range of polymer seed particles used in "dynamic swelling method" (DSM), first it was verified theoretically that the submicron-sized polymer particles produced by emulsion polymerization can also absorb a large amount of monomer by DSM in both equilibrium and k
The thermodynamic simulation under the kinetic control state indicates that 1.77-m-sized monodispersed polystyrene (PS) particles can absorb 500 times the amount of the styrene monomer with keeping the monodispersity by the "dynamic swelling method" (DSM) which the authors proposed in 1991. Actually