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Thermochemistry of carbonyl addition reactions. I. Addition of water and methanol to hexafluoroacetone

โœ Scribed by Rogers, F. E.; Rapiejko, R. J.


Book ID
126880215
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
264 KB
Volume
93
Category
Article
ISSN
0002-7863

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The addition of methyl radicals to hexaf
โœ L. Batt; S. I. Mowat ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 558 KB

The reaction of methyl radicals (Me) with hexafluoroacetone (HFA), generated from ditertiary butyl peroxide (dtBP), was studied over the temperature range of 402-433 K and the pressure range of 38-111 torr. The reaction resulted in the following displacement process taking place: where TFA refers t