The kinetics of the addition of alkyl ra
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Roger M. Drew; J. Alistair Kerr
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Article
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1983
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John Wiley and Sons
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English
β 509 KB
By pyrolyzing di-t-butyl peroxide over the temperature range of 405-450 K in the presence of hexafluoroacetone the kinetics of the addition reaction (l), CH3 + (CF3)zCO + (CF3)&(O)CH3, have been studied. Detailed analyses have shown that the principal product of the adduct radical, (CF3)&(O)CH3, is