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Complex Formation by Fluoroketones. I. Addition of Hexafluoroacetone to Hydrides of Group IV Elements

✍ Scribed by Cullen, W. R.; Styan, G. E.


Book ID
126329158
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
494 KB
Volume
4
Category
Article
ISSN
0020-1669

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By pyrolyzing di-t-butyl peroxide over the temperature range of 405-450 K in the presence of hexafluoroacetone the kinetics of the addition reaction (l), CH3 + (CF3)zCO + (CF3)&(O)CH3, have been studied. Detailed analyses have shown that the principal product of the adduct radical, (CF3)&(O)CH3, is