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Thermochemical Properties, Pathway, and Kinetic Analysis on the Reactions of Benzene with OH: An Elementary Reaction Mechanism

โœ Scribed by Chen, Chiung-Chu; Bozzelli, Joseph W.; Farrell, John T.

Book ID
121421533
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
891 KB
Volume
108
Category
Article
ISSN
1089-5639

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Chemical activation and unimolecular dissociation pathway kinetic analysis is presented on addition of radicals H, O, OH, and HO 2 to one of the two types of unsaturated carbons on cyclopentadiene. Addition of H atom or OH radical at the 1 position forms an allylic radical, which can break the weake