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Thermally induced incomplete high-spin (5T2) ⇌ low-spin (1AJ) transition in dithiocy anatobis (n-phenyl-2-pyridinaldimine) iron (II)

✍ Scribed by E. König; G. Ritter; R. Schnakig

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
288 KB
Volume
27
Category
Article
ISSN
0009-2614

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✦ Synopsis

57Fe hlijssbauer spectn bctwcen 4.2 and 298°K and magnetic data 'UC employed to dcmonstratc that Fe(ppi)2(NCS)2 exhibits a thermally induced high-spin (5T2) = low-spin ('A,) kansition associated with ;1 residual fraction 1(5Tz) =Z 0.59 (ppi = N-phcnyl-Z-pyridinaldhnine).

ln the relalcd compound Fe(pti)3(C104)2. hiijssbaucr spectrn typical of il 'A, ground state arc observed.

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