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Thermal unimolecular decomposition of β-propiolactone (oxetan-2-one)

✍ Scribed by Frey, H. Monty; Pidgeon, Ivy M.


Book ID
121290354
Publisher
The Royal Society of Chemistry
Year
1985
Weight
656 KB
Volume
81
Category
Article
ISSN
0300-9589

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On the thermal unimolecular decompositio
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The thermal unimolecular decomposition of propynal was investigated behind reflected shock waves. The decomposition proceeded via the molecular path to produce acetylene and carbon monoxide. The Arrhenius expression for the high pressure rate constants is k, = 10'4.93 exp ( -7 1 kcal mol-'/RT) s-' i