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Thermal unimolecular decomposition of β-butyrolactone (4-methyloxetan-2-one)

✍ Scribed by Frey, Henry M.; Watts, Hugo P.

Book ID
121290353
Publisher
The Royal Society of Chemistry
Year
1983
Weight
720 KB
Volume
79
Category
Article
ISSN
0300-9589

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The unimolecular decomposition of 3,4dihydro-2H-pyran was investigated behind reflected shock waves by monitoring infrared absorption at 9.44 pm. The decomposition proceeded via a direct molecular process to ethylene and acrolein. The Arrhenius expression for the decomposition rate constant, k= IO"-