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Thermal, structural and textural studies on the double complex salt [Co(NH3)6][Fe(CN)6] and on its silica-supported catalysts

✍ Scribed by L. H. Khalil; N. A. Mousssa; S. Mikhail


Publisher
Springer
Year
1992
Tongue
English
Weight
915 KB
Volume
27
Category
Article
ISSN
0022-2461

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Asymmetric salt effects on anion/cation
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## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4βˆ’^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3βˆ’^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__