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Thermal Rearrangements of Monoterpenes and Monoterpenoids

✍ Scribed by Achim Stolle; Bernd Ondruschka; Henning Hopf

Book ID: 102858109
Publisher: John Wiley and Sons
Year: 2009
Tongue: German
Weight: 552 KB
Volume: 92
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.200900041

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✦ Synopsis

Abstract

The thermal conversions of monoterpenes and monoterpenoids are an interesting field of research with respect to mechanistic, kinetic, and theoretical issues. Since the beginning of the 20th century, these reactions have attracted the interest of many research groups, and even today there are sufficient problems and questions to deal with. This review covers the thermal isomerization chemistry of pinanes, pinenes, carenes, and thujenes over the past 70 years. Categorization of these compounds into groups, each of them being represented by a small parent molecule (cyclobutane, vinylcyclobutane, vinylcyclopropane), allows systematization of multitude of publications.

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