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Thermal Behaviour of Selected C10H16 Monoterpenes

✍ Scribed by Achim Stolle; Claudia Brauns; Matthias Nüchter; Bernd Ondruschka; Werner Bonrath; Matthias Findeisen

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
258 KB
Volume
2006
Category
Article
ISSN
1434-193X

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✦ Synopsis

Abstract

The presented work investigates the thermal behaviour of selected monoterpenes under various reactor temperatures and residence times (carrier gas, reactor inserts). In addition to the analysis of the liquid products by capillary GC and GC‐MS, chemical derivatisation techniques (Diels–Alder reaction, hydrogenation) were used to identify the liquid‐phase products. A thermal conversion of β‐pinene (1), myrcene (2) and limonene (4) in a reaction network is presented and the experimental evidence for the formation of pyrolysis products by a biradical pathway is discussed. The reaction network was modified based on the identification of additional C~10~H~16~ terpene isomers. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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