Thermal rearrangement of N-acetyl-N-nitrosoneuraminic acid derivative: Synthesis of 3-deoxy-D-Nonulosonic acid (KDN)
โ Scribed by Ryuichi Shirai; Mitsunobu Nakamura; Sumiko Hara; Hiroaki Takayanagi; Haruo Ogura
- Book ID
- 104216645
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 187 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Thermal rearrangement of E-acetyl-l&nitrosoneuraminic acid derivative followed by deprotection gave 3-deoxy-&nonulosonic acid (KDN).
Recently, an unknown acidic sugar was isolated by Inoue etc.
๐ SIMILAR VOLUMES
A Novel Glycosylation of 3-Deoxy-D-glycero-D-galacto-2-nonulosonic Acid (KDN) via in situ Pyranose-Furanose Rearrangement. -The title glycosylation is examined in more detail. A proposed mechanism for the ring contracted KND-derivative (V) is discussed. It is noteworthy that all yields are lower if
The reaction of the peracetate methyl esters of N-acetylneuraminic acid (Neu5Ac), 3-deoxyq~glycero-D-galacto-2-nonulosonic acid (Kdn), and 3-deoxy-D-manno-2-octulosonic acid (Kdo) with trimethylsilyl trifluoromethanesulfonate (CF3SO3SiMe 3) has been reinvestigated. We have found that the choice of s