Pentacyclic (CH)a hydrocarbon 1 can be viewed not only as the most highly condensed valence isomer of cyclooctatetraene, but also as a formal (2+2) dimer of tetrahedrane. The effective cyclic conjugation of two bicyclo[l.l.O]butsne rings in 1 should form the basis for interesting spectral properties
β¦ LIBER β¦
Thermal rearrangement of dibromotetracyclo[5.1.0.02,4.03,5]octanes. Assessment of the competitive opening of dibromocyclopropane and bicyclo[1.1.0]butane rings and a general synthesis of trans-bishomobenzenes
β Scribed by Taylor, Richard T.; Paquette, Leo A.
- Book ID
- 126824656
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 405 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0002-7863
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## Abstract Alkalische Zersetzung der bisβ__p__βToluolβsulfonylhydrazone **3** und **4** von sowohl __anti__β (**1**) wie auch __syn__βBisβhomoβ__p__βchinon (**2**) ergab 4,5βHomoβ1,7βdiazaβinden (**5**). Das Produkt hat Eigenschaften eines Pyrazols und eines Olefins. Durch katalytische Reduktion e