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Thermal rearrangement of dialkyl (3-ketobutyl)phosphites

✍ Scribed by M. I. Rizpolozhenskii; F. S. Mukhametov


Book ID
112432072
Publisher
Springer
Year
1968
Tongue
English
Weight
49 KB
Volume
17
Category
Article
ISSN
1573-9171

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The thermal rearrangement of diethyl Ξ±-m
✍ Anthony L. Lemper; Howard Tieckelmann πŸ“‚ Article πŸ“… 1964 πŸ› Elsevier Science 🌐 French βš– 322 KB

Rearrangements of diethyl a-methylallyl phosphite (I) and diethyl crotyl phosphite (II) have recently been reported by Pudovik and Aladshyeva (1,2) to give only the products resulting from inversion of the migrating allylic groups. They accounted for the products by an intramolecular rearrangement (