Reactions of 1,2,4-Trithiolane and Its 4
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Holm Petzold; Thomas Weisheit; Silvio Bräutigam; Helmar Görls; Grzegorz Mloston;
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Article
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2010
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John Wiley and Sons
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English
⚖ 301 KB
## Abstract Reactions of 1,2,4‐trithiolanes with Pt^0^ complexes often proceed via an oxidative addition of the Pt^0^ complex fragment into the S–S bond and subsequent extrusion of a thioketone molecule by ring contraction. The six‐membered intermediate **5a**, formed in the course of the reaction