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Thermal Reactions of Regioisomeric 1,2,4-Trithiolane S-Oxides

✍ Scribed by Grzegorz Mloston; Jaroslaw Romanski; Michael L. McKee; Hans Peter Reisenauer; Peter R. Schreiner


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
477 KB
Volume
2010
Category
Article
ISSN
1434-193X

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Reactions of 1,2,4-Trithiolane and Its 4
✍ Holm Petzold; Thomas Weisheit; Silvio Bräutigam; Helmar Görls; Grzegorz Mloston; 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 301 KB

## Abstract Reactions of 1,2,4‐trithiolanes with Pt^0^ complexes often proceed via an oxidative addition of the Pt^0^ complex fragment into the S–S bond and subsequent extrusion of a thioketone molecule by ring contraction. The six‐membered intermediate **5a**, formed in the course of the reaction