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Oxidation of Spirocyclohexyl-1,2,4-trithiolane and Complexation Reaction with [Pt(η2-nb)(PPh3)2]

✍ Scribed by Holm Petzold; Silvio Bräutigam; Helmar Görls; Wolfgang Weigand; Jaroslaw Romanski; Grzegorz Mloston


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
167 KB
Volume
2007
Category
Article
ISSN
1434-1948

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Reactions of 1,2,4-Trithiolane and Its 4
✍ Holm Petzold; Thomas Weisheit; Silvio Bräutigam; Helmar Görls; Grzegorz Mloston; 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 301 KB

## Abstract Reactions of 1,2,4‐trithiolanes with Pt^0^ complexes often proceed via an oxidative addition of the Pt^0^ complex fragment into the S–S bond and subsequent extrusion of a thioketone molecule by ring contraction. The six‐membered intermediate **5a**, formed in the course of the reaction